Cycloaddition to an anthracene-derived macrocyclic receptor with supramolecular control of regioselectivity.
نویسندگان
چکیده
N-Ethylmaleimide and maleic anhydride add to the interior face of one anthracene wall with unusual 1,4-regioselectivity, whereas singlet oxygen adds to both anthracene walls with 9,10-regioselectivity.
منابع مشابه
Cycloaddition to an anthracene-derived macrocyclic receptor with supramolecular control of regioselectivityw
Recently, we described the preparation of anthracenecontaining macrocyclic tetralactams 1a and 1b and showed that they can encapsulate squaraine dyes with high affinity in a range of solvent systems, including the interior of living cells. The expanding literature on anthracene-containing receptors suggests that members of the compound family 1 may be versatile structural components in various ...
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ورودعنوان ژورنال:
- Chemical communications
دوره 18 شماره
صفحات -
تاریخ انتشار 2009